Synthesis and photoluminescence characteristics of Dy incorporated MoO3 phosphor: Suppression concentration quenching

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Tarih

2020

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Yayıncı

Elsevier Ltd

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

A series of MoO3:Dy3+ phosphors have been synthesized via the gel-combustion method. The X-ray and photoluminescence (PL) emission spectra were employed to characterize the obtained phosphors. The prepared samples were characterized through XRD measurements and exhibited that Dy3+ ions can be successfully incorporated into the host material. The PL emission bands of Dy3+ doped MoO3 were observed at 486 nm, 574 nm and 666 nm which are assigned to the transitions of 4F9/2 ? 6H15/2, 4F9/2 ? 6H13/2 and 4F9/2 ? 6H11/2, respectively. Concentration quenching were largely taken into consideration as one of the crucial aspects limiting the application range of phosphors in today's modern world. An abnormal thermal quenching dependence was reported when Dy3+ ions were incorporated into MoO3 host matrix. In order to understand the origin of this beneficial behaviour, energy transfer processes occurring via radiative and nonradiative mechanisms were investigated to elucidate this suppression of the concentration quenching. © 2020 Elsevier Ltd

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Anahtar Kelimeler

Gel-combustion method, MoO3, Photoluminescence, Quenching, XRD, Emission spectroscopy, Energy transfer, Molybdenum oxide, Phosphors, Photoluminescence, Quenching, Application range, Concentration quenching, Energy transfer process, Gel-combustion method, Photoluminescence characteristics, Photoluminescence emission, Thermal quenching, XRD measurements, Dysprosium, metal oxide, molybdenum trioxide, phosphorus, unclassified drug, Article, controlled study, isotope labeling, mathematical computing, mathematical model, photochemical quenching, photoluminescence, priority journal, synthesis, X ray diffraction

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